The opposite of "chum with" can be expressed through various antonyms such as "distant," "cool," "aloof," or "estranged." These terms suggest a lack of intimacy, friendship, or camaraderie between individuals, indicating that they are not particularly fond of each other or may even harbor negative feelings towards one another. Other antonyms can include "divided," "detached," "isolated," "separated," and "disconnected." Each of these words conjures an image of distance and separation, emphasizing the lack of closeness or familiarity between people who are not chums. Whether due to personal differences, competition, or circumstance, the absence of a chummy relationship can be both uncomfortable and insurmountable.